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Asian Journal of Physics Vol 31, Nos 9 – 10 (2022) 905-912

Probing intermolecular interactions in a binary mixture of deep eutectic solvents with DMSO by impulsive stimulated Raman spectroscopy

Garima Bhutani, Vivek Yadav, Anita Yadav and Arijit K De
Condensed Phase Dynamics group, Department of Chemical Sciences,
Indian Institute of Science Education and Research (IISER) Mohali Knowledge City, Sector 81, SAS Nagar, PB 140 306, India

The physicochemical properties of deep eutectic solvents (DESs) can be altered in binary mixture with co-solvents like water, dimethyl sulfoxide (DMSO), etc. due to the synergistic effect of hydrogen bond donors-acceptors (HBDs- HBAs) that arises from the interactions of DESs with (organic) solvents. We investigated the intermolecular interactions of DES (1,3-Propanediol-based) of varying compositions in binary mixture with DMSO and observed the emergence of a new vibrational mode using impulsive stimulated Raman spectroscopy (ISRS). © Anita Publications. All rights reserved.
Keywords: Deep eutectic solvents (DESs), Binary mixture, Hydrogen bond interactions, Intermolecular interactions, Impulsive stimulated Raman spectroscopy (ISRS).
DOI: https://doi.org/10.54955/AJP.31.9-10.2022.905-912

Peer Review Information
Method: Single- anonymous; Screened for Plagiarism? Yes
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