Asian Journal of Physics Vol. 34, Nos 1 & 2 (2025) 1-8

The effect of patterned quantum dot films on the optical properties of white LEDs studied by optical simulation and experiment

Jaehyeong Yoo, Seung Chan Hong, Sung Min Park, Sung-Yoon Joe, and Jae-Hyeon Ko
School of Semiconductor-Display Technology, Nano Convergence Technology Center,
Hallym University, Chuncheon 24252, Gangwondo, Korea


Quantum dots (QDs) play a crucial role in display technology in terms of color purity. Due to their narrow emission spectrum, the color gamut of displays can be significantly enhanced. Additionally, QD materials can be utilized in general lighting to improve color rendering performance. In particular, red QDs can be integrated into remote components and applied to white LEDs to enhance their color rendering properties. In this study, we investigated the effect of patterned QD films on the optical characteristics of white LEDs through optical simulations and experiments. Initially, in the simulation, red QD particles were mixed with TiO2 nanoparticles in the diffuser plate placed above the white LED array. The simulation revealed that achieving high color rendering lighting with red QDs requires an appropriate mixture of TiO2 nanoparticles and QD particles. Consequently, a higher QD concentration was needed as the QD film area decreased. The experimental implementation of patterned QD films on the lighting device demonstrated that appropriate patterning enables high luminance while maintaining acceptable color rendering performance. Moreover, this approach can be employed to widely adjust the correlated color temperature of the white LED device. This study presents an innovative design strategy for realizing high-color-rendering white LEDs while reducing QD consumption and overall costs. © Anita Publications. All rights reserved.
Doi: XXX
Keywords: Quantum dot, LED, Lighting device, Color rendering.


Peer Review Information
Method: Single- anonymous; Screened for Plagiarism? Yes
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References

  1. Schubert E F, Kim J K, Luo H, Xi J Q, Solid-state lighting—A benevolent technology, Rep Prog Phys, 69(2006) 3069.
  2. McKittrick J, Shea-Rohwer L E, Down conversion materials for solid-state lighting, J Am Ceram Soc, 97(2014)97, 1327–1352.
  3. Erdem T, Demir H V, Color science of nanocrystal quantum dots for lighting and displays, Nanophotonics, 2(2013)57–81.
  4. Bae W K, Lim J, Lee D, Park M, Lee H, Kwak J, Char K, Lee C, Lee S, R/G/B/natural white light thin colloidal quantum dot-based light-emitting devices, Adv Mater, 26(2014)6387–6393.
  5. Lim S J, Zahid M U, Le P, Ma L, Entenberg D, Harney A S, Condeelis J, Smith A M, Brightness-equalized quantum dots, Nat Commun, 6(2015)8210; doi.org/10.1038/ncomms9210.
  6. Lim J, Park Y S, Wu K, Yun H J, Klimov V I, Droop-free colloidal quantum dot light-emitting diodes, Nano Lett, 18 (2018)6645–6653.
  7. Lien J Y, Chen C J, Chiang R K, Wang S L, High color-rendering warm-white lamps using quantum-dot color conversion films, Opt Express, 24(2016)A1021–A1032.
  8. Kim J H, Jo D Y, Lee K H, Jang E P, Han C Y, Jo J H, Yang H, White electroluminescent lighting device based on a single quantum dot emitter, Adv Mater, 28(2016)5093–5098.
  9. Yoon H C, Oh J H, Lee S, Park J B, Do Y R, Circadian-tunable perovskite quantum dot-based down-converted multi-package white LED with a color fidelity index over 90, Sci Rep, 7(2017)2808; doi.org/10.1038/s41598-017-03063-7.
  10. Kim J H, Kim B Y, Jang E P, Han C Y, Jo J H, Do Y R, Yang H, A near-ideal color rendering white solid-state lighting device copackaged with two color-separated Cu–X–S (X= Ga, In) quantum dot emitters, J Mater Chem C, 5(2017)6755–6761.
  11. Zhang H, Su Q, Chen S, Quantum-dot and organic hybrid tandem light-emitting diodes with multi-functionality of full-colortunability and white-light-emission, Nat Commun, 11(2020)2826; doi.org/10.1038/s41467-020-16659-x.
  12. Rhee S, Kim K, Roh J, Kwak J, Recent progress in high-luminance quantum dot light-emitting diodes, Curr Opt Photon, 4(2020)161–173.
  13. Li B, Lu M, Feng J, Zhang J, Smowton P M, Sohn J I, Park I K, Zhong H, Hou B, Colloidal quantum dot hybrids: An emerging class of materials for ambient lighting, J Mater Chem C, 8(2020)10676–10695.
  14. Hong A, Kim J, Kwak J, Sunlike White Quantum Dot Light-Emitting Diodes with High Color Rendition Quality, Adv Opt Mater, 8(2020)200105; doi.org/10.1002/adom.202001051.
  15. Lee J, Sundar V C, Heine J R, Bawendi M G, Jensen K F, Full color emission from II–VI semiconductor quantum dot–polymer composites Adv Mater, 12(2000)1102–1105.
  16. Zhang H, Cui Z, Wang Y, Zhang K, Ji X, Lü C, Yang B, Gao M, From water-soluble CdTe nanocrystals to fluorescent nanocrystal–polymer transparent composites using polymerizable surfactants Adv Mater, 15(2003)777–780.
  17. Li C, Murase N, Synthesis of Highly Luminescent Glasses Incorporating CdTe Nanocrystals through Sol-Gel Processing, Langmuir, 20(2004)1–4.
  18. Bullen C, Mulvaney P, Sada C, Ferrari M, Chiasera A, Martucci A, Incorporation of a highly luminescent semiconductor quantum dot in ZrO2–SiO2 hybrid sol–gel glass film, J Mater Chem, 14 (2004)1112–1116.
  19. Wang Q, Iancu N, Seo D K, Preparation of large transparent silica monoliths with embedded photoluminescent CdSe@ZnS core/shell quantum dots, Chem Mater, 17(2005)4762–4764.
  20. Neves M C, Martins M A, Soares-Santos P C, Rauwel P, Ferreira R A, Monteiro T, Carlos LD, Trindade T, Photoluminescent, transparent and flexible di-ureasil hybrids containing CdSe/ZnS quantum dots, Nanotechnology, 19(2008)155601; doi 10.1088/0957-4484/19/15/155601.
  21. Tetsuka H, Ebina T, Mizukami F, Highly luminescent flexible quantum dot–clay films, Adv Mater, 20(2008) 3039–3043.
  22. Mutlugun E, Hernandez-Martinez P L, Eroglu C, Coskun Y, Erdem T, Sharma V K, Unal E, Panda S K, Hickey S G, Gaponik N, Eychmüller N, Demir H V, Large-area (over 50 cm 50 cm) freestanding films of colloidal InP/ZnS quantum dots, Nano Lett, 12(2012)3986–3993.
  23. Jun S, Lee J, Jang E, Highly luminescent and photostable quantum dot–silica monolith and its application to light-emitting diodes, ACS Nano, 7(2013)1472–1477.
  24. Kim J.-H, Yang H, White lighting device from composite films embedded with hydrophilic Cu(In, Ga)S2/ZnS and hydrophobic InP/ZnS quantum dots, Nanotechnology, 25(2014)225601; doi. 10.1088/0957-4484/25/22/225601 .
  25. Lee S H, Lee K H, Jo J H, Park B, Kwon Y, Jang H S, Yang H, Remote-type, high-color gamut white light-emitting diode based on InP quantum dot color converters, Opt Mater Exp, 4(2014)1297–1302.
  26. Altintas Y, Genc S, Talpur M Y, Mutlugun E, CdSe/ZnS quantum dot films for high performance flexible lighting and display applications, Nanotechnology, 27(2016)295604; doi. 10.1088/0957-4484/27/29/295604.
  27. Yu S, Fritz B, Johnsen S, Busko D, Richards B S, Hippler M, Wiegand G, Tang Y, Li Z, Lemmer U, Hölscher H, Gomard G, Enhanced photoluminescence in quantum dots–porous polymer hybrid films fabricated by microcellular foaming, Adv Opt Mater, 7(2019)1900223; doi.org/10.1002/adom.201900223.
  28. Kim G Y, Kim S, Choi J, Kim M, Lim H, Nam T W, Choi W, Cho E N, Han H J, Lee C H, Kim J C, Young H, Sung-Yool J, Seok C M, Duk J, Jeon Y, Jung Y S, Order-of-magnitude, broadband-enhanced light emission from quantum dots assembled in multiscale phase-separated block copolymers, Nano Lett, 19(2019)6827–6838.
  29. Hong S C, Gwak S T, Park S, Lee G J, Lee J G, Ko J H, Joe S Y, Kim Y, Park T, Ko Y W, Improvement of color-rendering characteristics of white light emitting diodes by using red quantum dot films, Curr Appl Phys, 31(2021) 199–207.
  30. Lee J G, Lee G J, Hong S C, Ko J H, Park T, Ko Y W, Shape optimization of quantum-dot caps for high color-rendering white light-emitting diodes studied by optical simulation, J Korean Phys Soc, 78(2021)822–828.
  31. Lee G J, Hong S C, Lee J G, Ko J H, Park T, Ko Y W, Lushnikov S, Substantial Improvement of Color-Rendering Properties of Conventional White LEDs Using Remote-Type Red Quantum-Dot Caps, Nanomater, 12(2022)1097; doi.org/10.3390/nano12071097.
  32. Hong S C, Ko, J.H. Structural Optimization of Vertically-Stacked White LEDs with a Yellow Phosphor Plate and a Red Quantum-Dot Film, Nanomater, 12(2022)2846; doi.org/10.3390/nano12071097.
  33. Baek E, Kim B, Kim S, Song J, Yoo J, Park S M, Lee J-M, Ko J.-H, Color rendering index over 95 achieved by using light recycling process based on hybrid remote-type red quantum-dot components applied to conventional LED lighting devices, Nanomater, 13(2023)2560; doi.org/10.3390/nano13182560.